AMPC  Vol.2 No.4 , December 2012
BPSCCO Superconducting Films Grown by Spray Pyrolysis Technique: Systematic Study of the Relationship between Pb Content and Annealing Conditions
Abstract: Actually recent investigation in developing semiconducting-superconducting composites based in CdS and Bi-based superconductors has attracted interest in processing thin superconducting films. In this work are reported Bi-Pb-Sr-Ca-Cu-O (BPSCCO) thin films grown on MgO substrates by spray pyrolysis technique from a solution containing Bi(NO3)3, Pb(NO3)2, Sr(NO3)2, Ca(NO3)2 and Cu(NO3)2, with a subsequent solid state reaction for growing the Bi-based superconducting phases. Annealed films were characterized by X-ray diffraction, atomic absorption spectroscopy and resistance measurements. Interdependence between Pb content, annealing time and temperature, in the formation of superconducting phases was studied applying a fractional factorial design 3III4-2. Interrelation between Pb content, ta and Ta exists. The presence of Pb is necessary to stabilize the high-Tc phase but its content depends on the annealing conditions.  
Cite this paper: Y. Valdés, C. Mejía García, A. Paniagua Mercado and A. Sánchez, "BPSCCO Superconducting Films Grown by Spray Pyrolysis Technique: Systematic Study of the Relationship between Pb Content and Annealing Conditions," Advances in Materials Physics and Chemistry, Vol. 2 No. 4, 2012, pp. 92-95. doi: 10.4236/ampc.2012.24B025.

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