AMPC  Vol.2 No.4 , December 2012
Polypyrrole Micro/Nanostructure Prepared Using Azo Dyes with Different Substituents

This contribution deals with simple way of polypyrrole structure modification. Using azo dyes in polymerization reaction as soft-template with similar molecular structure but different type and distribution of substitution groups lead to formation of one-dimensional and newly also three-dimensional polypyrrole micro/nanostructures. These structures are characteristic with geometrical symmetry and uniformity. Geometry of prepared structures was studied by scanning electron microscopy (SEM) and by methods of image analysis; nanotubes are hundreds of nm in diameter and units of μm in length, new tree-dimensional structures have units of μm in diameter. Infrared spectra (ATR-FTIR) confirmed that azo dyes work only as intermediate supporting structures without reaction with polypyrrole.




Cite this paper
D. Kopecky, J. Skodova, M. Vrnata and P. Fitl, "Polypyrrole Micro/Nanostructure Prepared Using Azo Dyes with Different Substituents," Advances in Materials Physics and Chemistry, Vol. 2 No. 4, 2012, pp. 89-91. doi: 10.4236/ampc.2012.24B024.
[1]   N. V. Blinova, J. Stejskal, M. Trhová, J. Prokes, M. Omastová, “Polyaniline and polypyrrole: A comparative study of the preparation”, Eur. Polym. J., vol. 43, pp. 2331-2341, 2007.

[2]   U. Lange, N. V. Roznyatovskaya, V. M. Mirsky, “Conducting polymers in chemical sensors and arrays”, Anal. Chimica Acta, vol. 614, pp. 1-26, 2008.

[3]   X. Yang, Z. Zhu, T. Dai, Y. Lu, “Nanotubes via a reactive self-degraded template”, Macromol. Rapid Commun.vol. 26, pp. 1736-1740, 2005.

[4]   D. Zhang, Y. Wang, “Synthesis and applications of one-dimensional nano-structured polyaniline: An overview”, Mater. Sci. Eng., B, vol. 134, pp. 9-19, 2006.