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 MSA  Vol.3 No.10 , October 2012
Bulk Composite Nanomaterial with Multiwall Carbon Nanotubes
Abstract: The properties of the composite nanomaterials (CNM) based on bovine serum albumin (BSA) and multi-walled carbon nanotubes (MWCNT), both functionalized and non-functionalized, were investigated. In order to obtain the solid-state bulk CNM from the ultradispersed aqueous solutions of 25 wt.% BSA and (0.0015 - 0.04) wt.% MWCNT, the methods of nanotechnology and laser technology were used. It is revealed that the CNM density is 10% - 20% higher than that of water and the hardness is higher than that of BSA by a factor of 3 - 6 times. An increase in hardness Hv (by Vickers) of CNM correlated with an increase in the concentration of MWCNT, and Hyreached ~300 MPa for the case of the non-functionalized MWCNT, while for the case of the functionalized MWCNT, i.e. MWCNTf, Hy was 25% lower.
Cite this paper: L. Ichkitidze, V. Podgaetsky, A. Prihodko, S. Selishchev, E. Blagov, V. Galperin, Y. Shaman and L. Tabulina, "Bulk Composite Nanomaterial with Multiwall Carbon Nanotubes," Materials Sciences and Applications, Vol. 3 No. 10, 2012, pp. 728-732. doi: 10.4236/msa.2012.310106.
References

[1]   N. Grobert, “Carbon Nanotubes—Becoming Clean,” Ma- terials Today, Vol. 10, No. 1-2, 2007, pp. 28-35. doi:10.1016/S1369-7021(06)71789-8

[2]   L. P. Ichkitidze and I. V. Komlev, “Carbon Nanotubes and Composite Nanomaterials: Toxicity,” Lasers in Sci- ence, Engineering, Medicine, No. 21, 2010, pp. 103-113.

[3]   J. Kolosnjaj-Tabi, K. B. Hartman, S. Boudjemaa, J. S. Ananta, G. Morgent, H. Swarc, L. J. Wilson and F. Moussa, “In Vivo Behavior of Large Doses of Ultrashort and Full-Length Single-Walled Carbon Nanotubes after Oral and Intraperitoneal Administration to Swiss Mice,” ACS Nano, Vol. 4, No. 3, 2010, pp. 1481-1492. doi:10.1021/nn901573w

[4]   K. Donaldson, R. Aitken, , L. Tran, V. Stone, R. Duffin, G. Forrest and A. Alexander, “Carbon Nanotubes: Review of Their Properties in Relation to Pulmonary Toxicology and Workplace Safety,” Toxicological Science, Vol. 92, No. 1, 2006, pp. 5-22. doi:10.1093/toxsci/kfj130

[5]   S. Magrez, V. Kasas, V. Salicio, N. Pasquier, J. W. Seo, M. Celio, S. Catsicas, B. Schwaller and L. Forro, “Cellular Toxicity of Carbon-Based Nanomaterials,” Nano Letters, Vol. 6, No. 6, 2006, pp. 1121-1125. doi:10.1021/nl060162e

[6]   S. Koyama, Y.-A. Kim, T. Hayashi, K. Takeuchi, C. Fujii, N. Kuroiwa, H. Koyama, R. Tsukahara and M. Endo, “In Vivo Immunological Toxicity in Mice of Carbon Nanotubes with Impurities,” Carbon, Vol. 47, No. 5, pp. 1365- 1372. doi:10.1016/j.carbon.2009.01.028

[7]   J. Muller, F. Huaux, N. Moreau, P. Misson, J. F. Heilier, M. Delos, M. Arras, A. Fonseca, J. B. Naqy and D. Lison, “Respiratory Toxicity of Multi-Walled Carbon Nanotubes,” Toxicology and Applied Pharmacology, Vol. 207, No. 3, 2005, pp. 221-231. doi:10.1016/j.taap.2005.01.008

[8]   I. A. Andreeva, V. B. Bagratashvili, L. P. Ichkitidze, V. M. Podgaetsky, O. V. Ponomareva, V. S. Savranskii and S. V. Selishchev, “Determination of Mechanical Properties of Biocompatible Three-Dimensional Nanocomposites Manufactured Using Laser Methods,” Biomedical Engineering, Vol. 43, No. 6, 2009, pp. 241-248.doi:10.1007/s10527-010-9134-4

[9]   L. P. Ichkitidze, V. M. Podgaetsky, O. V. Ponomareva and S. V. Selishchev, “Mechanical Properties of Bulk Nanocomposite Obtained by Laser Irradiation,” Izvestiya VUZov. Physica (Russia), Vol. 53, No. 3/2, 2010, pp. 125-129.

[10]   S. A. Ageeva, V. I. Eliseenko, A. Yu. Gerasimenko, L. P. Ichkitidze, V. M. Podgaetsky and S. V. Selishchev, “Possible Medical Application of Laser Nanoengineering,” Biomedical Engineering, Vol. 44, No. 6, 2011, pp. 233- 236. doi:10.1007/s10527-011-9195-z

[11]   A. Yu. Gerasimenko, O. V. Gubar’kov, L. P. Ichkitidze, V. M. Podgaetskii, S. V. Selishchev and O. V. Ponoma- reva, “Nanocomposite Solder for Laser Welding of Biological Tissues,” Semiconductors, Vol. 45, No. 13, pp. 1713-1718. doi:10.1134/S1063782611130112

[12]   X. Zhao, R. Liu, Z. Chi, Y. Teng and P. Qin, “New Insightsinto Behavior of Bovine Serum Albumin Adsorbed onto Carbon Nanotubes: Comprehensive Spectroscopic Studies,” Journal of Physical Chemistry B, Vol. 114, No. 16, 2010, pp. 5625-5631.

[13]   Y.-P. Sun, K. Fu, Y. Lin and W. Huang, “Functionalized Carbon Nanotubes: Properties and Applications,” Accounts of Chemical Research, Vol. 35, No. 12, 2002, pp. 1096-1104. doi:10.1021/ar010160v

[14]   N. V. Glebov and A. A. Nechitailov, “Functionalization of the Surfacemultiwalled Carbon Nanotubes,” Technical Physics Letters (Russia), Vol. 36, No. 19, 2010, pp. 8-15.

[15]   M. Berkei, “Conductive Coatings Using Carbon Nanotubes: A Fascinating Material for the Coating Producer’s Toolbox,” CHEManager Europe, 7-8/2011, 2011, p. 10. www.chemanager-online.com/en/tags/coatings

 
 
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