AJAC  Vol.3 No.9 , September 2012
3D Fluorescence Characterization of Synthetic Organic Dyes
Abstract: The identification of dyes is important in research on museum artefacts as well as in forensic applications. UV-visible absorption spectroscopy cannot unambiguously distinguish dyes with similar hues, while mass spectrometry may fail to distinguish isobaric dyes. The detailed patterns produced by 3D fluorescence spectroscopy appear to be virtually unique, even among dyes that are closely related positional isomers. We report these patterns for 65 dyes from the Schweppe Library of Synthetic Organic Dyes as well as measurements suggesting both the capabilities and limitations of this method.
Cite this paper: L. Soltzberg, S. Lor, N. Okey-Igwe and R. Newman, "3D Fluorescence Characterization of Synthetic Organic Dyes," American Journal of Analytical Chemistry, Vol. 3 No. 9, 2012, pp. 622-631. doi: 10.4236/ajac.2012.39081.

[1]   Boston Museum of Fine Arts, “Chilkat Dancing Blanket,” Museum of Fine Arts, Boston, 2008.

[2]   L. J. Soltzberg, A. Hagar, S. Kridaratikorn, A. Mattson and R. Newman, “MALDI-TOF Mass Spectrometric Identification of Dyes and Pigments,” Journal of the American Society for Mass Spectrometry, Vol. 18, No. 11, 2007, pp. 2001-2006. doi:10.1016/j.jasms.2007.08.008

[3]   M. Clarke, “A New Technique for the Non-Destructive Identification of Organic Pigments, Dyes and Inks in-situ on Early Mediaeval Manu-scripts, Using 3-D Fluorescence Reflectance Spectroscopy,” Proceedings of the 6th International Conference on Non-Destructive Testing and Microanalysis for the Diagnostics and Conservation of the Cultural and Environmental Heritage ART’99, Rome, May 1999, pp. 1421-1436.

[4]   M. R. van Bommel, I. Vanden Berghe, A. M. Wallert, R Boitelle, J. Wouters, “High-Performance Liquid Chromatography and Non-Destructive Three-Dimensional Fluorescence Analysis of Early Synthetic Dyes,” Journal of Chromatography A, Vol. 1157, No. 1-2, 2007, pp. 260-272. doi:10.1016/j.chroma.2007.05.017

[5]   S. Shimoyama, Y. Noda and S. Kasuhara, “Non-Destructive Analysis of Ukiyo-E Prints,” In: P. W. Rogers, Ed., Dyes in History and Archaeology: 15, Textile Research Associates, York, 1996.

[6]   Schweppe Collection of Important Early Synthetic Dyes (Getty Conservation Institute, Los Angeles, CA). “Practical Information for the Identification of Early Synthetic Dyes,” Conservation Analytical Laboratory, Smithsonian Institution, Washington DC, 1987.

[7]   L. J. Soltzberg, J. D. Slinker, S. Flores-Torres, D. A. Bernards, G. G. Malliaras, H. D. Abruna, J.-S. Kim, R. H. Friend, M. D. Kaplan and V. Goldberg, “Identification of a Quenching Species in Ruthenium Tris-Bipyridine Electroluminescent Devices,” Journal of the American Chemical Society, Vol. 128, No. 24, 2006, pp. 7761-7764. doi:10.1021/ja055782g

[8]   F. J. Green, “The Sigma-Aldrich Handbook of Stains, Dyes and Indicators,” Aldrich Chemical Company, Milwaukee, 1990.

[9]   T. G. Adiks, A. F. Bunkin, V. A. Luk’yanchenko and S. M. Pershin, “Variation in the Fluorescent Background in Raman Spectra of Distilled Water Purified by Different Methods,” Physics of Wave Phenomena, Vol. 16, 2008, pp. 1-6.

[10]   L. V. Belovolova, M. V. Glushkov, E. A. Vinogradov, V. A. Babintsev and V. I. Golovanov, “Ultraviolet Fluorescence of Water and Highly Diluted Aqueous Media,” Physics of Wave Phenomena, Vol. 17, No. 1, 2009, pp. 21-31. doi:10.3103/S1541308X0901004X

[11]   M. Clarke, “Limitations of Fluorescence Spectroscopy as a Tool for Non-Destructive in situ Identification of Organic Pigments, Dyes and Inks,” Presented at 7th International Conference on Non-Destructive Testing and Microanalysis for Diagnostics and Conservation of Cultural and Environmental Heritage, Antwerp, 2-6 June 2002.

[12]   R. L. Feller, M. Curran and C. Bailie, “Identification of Traditional Organic Colorants in Japanese Prints and Determination of Their Rates of Fading,” In: R. S. Keyes, Ed., Japanese Woodblock Prints: A Catalogue of the Mary A. Ainsworth Collection, Allen Memorial Art Museum, Oberlin College, Oberlin, 1984.

[13]   “Hitachi High-Technologies Corporation Fluorescence Spectrophotometer Instruction Manual-FL Solutions Program-Operation,” 3rd Edition, Hitachi High-Technologies Corporation, 24-14, Nishi-Shimbashi 1-chome, Minatoku, Tokyo, 2001.

[14]   M. Strohalm, M Hassman, B. Kosata, M. Kodícek, “mMass Data Miner: An Open Source Alternative for Mass Spectrometric Data Analysis,” Rapid Communications in Mass Spectrometry, Vol. 22, No. 6, 2008, pp. 905-908. doi:10.1002/rcm.3444