JMP  Vol.3 No.9 , September 2012
Time-of-Flight Mass Spectrometry of Highly Ordered Carbyne
Matrix-assisted laser desorption/ionization (MALDI) time-of-flight mass spectrometry was applied to a non-conven-tional object–highly ordered carbyne films. Mass spectra of both positive and negative ions were recorded in all tests. The spectra had a rather high number of hydrogen atom peaks and specific features indicative of hydrogen acting as a requisite stabilizer in the crystalline carbyne structure. A new model based on interchain dihydrogen bonds was proposed.

Cite this paper
Y. Prazdnikov, "Time-of-Flight Mass Spectrometry of Highly Ordered Carbyne," Journal of Modern Physics, Vol. 3 No. 9, 2012, pp. 895-901. doi: 10.4236/jmp.2012.39117.
[1]   A. M. Sladkov, V. I. Kasatochkin, V. V. Korshak, et al., “Inventor’s Certificate No. 107 (December 7, 1971),” Bulletin Izobrebereteny, No. 6, 1972, p. 3.

[2]   Yu. P. Kudryavtsev, M. B. Guseva and V.G. Babaev, “Oriented Carbyne Layers,” Carbon, Vol. 30, No. 2, 1992, pp. 213-221. doi:10.1016/0008-6223(92)90082-8

[3]   R. B. Heimann, S. E. Evsyukov and L. Kavan, “Carbyne and Carbynoid Structures,” Kluwer, Dordrecht, 1999. doi:10.1007/978-94-011-4742-2

[4]   C. S. Casari, et al. “Chemical and Thermal Stability of Carbyne-Like Structures in Cluster-Assembled Carbon Films,” Physical Review B, Vol. 69, 2004, Article ID: 075422. doi:10.1103/PhysRevB.69.075422

[5]   V. Babaev, M. Guseva, V. Khvostov, N. Novikov and P. Flood, “Carbon Material with Highly Ordered Linear-Chain Structure, in ‘POLYYNES-Synthesis, Properties, Applications’,” CRC press, Boca Raton, 2005, pp. 219-252.

[6]   Yu. Prazdnikov, “Prospects of Carbyne Applications in Microelectronics,” Journal of Modern Physics, Vol. 2, No. 8, 2011, pp. 845-848. doi:10.4236/jmp.2011.28100

[7]   W. Luo and W. Windl, “First Principles Study of Structure and Stability of Carbynes,” Carbon, Vol. 47, No. 2, 2009, pp. 367-383. doi:10.1016/j.carbon.2008.10.017

[8]   Yu. G. Korobov and D. I. Bazhanov, “Ab initio Research on the Structure of Linear-Chain Carbon Oriented Films,” JETP Letters, Vol. 95, No. 9, 2012, p. 524.

[9]   J. E. Drut and T. A. L?hde, “Is Graphene in Vacuum an Insulator?” Physical Review Letters, Vol. 102, 2009, Article ID: 026802. doi:10.1103/PhysRevLett.102.026802

[10]   J. G. Korobova and D. I. Bazhanov, “Effect of Hydrogen on the Formation of the Atomic Structure of Linear Carbon Chains: An ab initio Approach,” Journal of Experimental and Theoretical Physics Letters, Vol. 93, No. 11, 2011, pp. 652-656. doi:10.1134/S0021364011110063

[11]   Yu. E. Prazdnikov, A. D. Bozhko and N. D. Novikov, “Energetic Barrier Reduction at the Carbyne Film Interface,” Journal of Russian Laser Research, Vol. 26, No. 1, 2005, pp. 55-65. doi:10.1007/s10946-005-0006-4

[12]   N. V. Belkova, L. M. Epstein and E. S. Shubina, “Dihydrogen Bonding, Proton Transfer and Beyond: What We Can Learn from Kinetics and Thermodynamics,” (Microreview), European Journal of Inorganic Chemistry, Vol. 2010, No. 23, 2010, pp. 3555-3565. doi:10.1002/ejic.201000546

[13]   Yu. E. Prazdnikov, L. S. Lepnev, A. D. Bozhko and N. D. Novikov, “Conductance Spectra of Carbyne Transverse to Carbon Chains. Is It Related to the Soliton Lattice?” Journal of Russian Laser Research, 2005, Vol. 26, No. 3, pp. 245-251. doi:10.1007/s10946-005-0017-1

[14]   M. J. Rice, S. R. Philpot, A. R. Bishop and D. K. Campbell, “Solitons, Polarons, and Phonons in the Infinite Po-lyyne Chain,” Physical Review B, Vol. 34, No. 6, 1986, p. 4139. doi:10.1103/PhysRevB.34.4139

[15]   S. W. McElvany, M. M. Ross and J. H. Callahan, “Characterization of Fullerenes by Mass Spectrometry,” Accounts of Chemical Research, Vol. 2, No. 3, 1992, pp. 162-168. doi:10.1021/ar00015a010