JMMCE  Vol.9 No.5 , May 2010
Growth and Characterization of Urea Adduct with m-Nitrobenzoic Acid,m-Nitroaniline, and p-Xylene Mixtures
Abstract: The urea adduct with the guests of m-nitrobenzoic acid, m-nitroaniline and p-xylene mixtures by adductive crystallization was successfully grown by slow evaporation method. The single crystals obtained were non-hygroscopic and good in size. The crystal structure of the grown crystal has been determined, and it belongs to the monoclinic system with centrosymmertic space group P21/c. Fourier transform infrared spectroscopic studies were performed for the identification of guest components in the compound. The optical absorption spectrum has been recorded in the range 200-1100 nm. The mechanical behavior of the specimen was studied.
Cite this paper: P. Jagdish, N. Rajesh and S. Natarajan, "Growth and Characterization of Urea Adduct with m-Nitrobenzoic Acid,m-Nitroaniline, and p-Xylene Mixtures," Journal of Minerals and Materials Characterization and Engineering, Vol. 9 No. 5, 2010, pp. 471-481. doi: 10.4236/jmmce.2010.95033.

[1]   David P. Shoemaker, Jerry Donohuem, Verner Schomaker, Robert B. Corey, 1950, “The Crystal Structure of Ls-Threonine.” J. Am. Chem. Soc. Vol. 72(6), pp. 2328-2349.

[2]   D.S. Chemla and J. Zyss, 1987, Nonlinear optical properties of organic molecules and crystals, Academic Press.

[3]   R.T. Denton, F.S. Chen, A.A. Ballman, 1967, “Lithium Tantalate Light Modulators” J. Appl. Phys. Vol. 38, pp. 1611-1617.

[4]   M. Ebrahimzadeh, M.H. Dunn, F. Akerboom, 1989, “Highly efficient visible urea optical parametric oscillator pumped by XeCl excimer laser” Optical Lett. Vol. 14, pp. 560-562.

[5]   D.J. Halfpenny, J.N. Sherwood, 1990, “Synchrotron-radiation section topography of large uncut crystals of organic nonlinear optical materials.” Philos. Msg. Lett. Vol. 62, pp. 1-7.

[6]   Joseph Zyss, 1982, “New organic molecular materials for nonlinear optics,” J. Non. Crystalline Solids, Vol. 47, pp. 211-225.

[7]   A.A. Gundyrev, L.P. Kazakova, M.V. Karaibog, 1977, “Influence of alcohols on ureaadduct formation with solid paraffins.” Chem. And Tech. of Fuels and Oils, Vol. 13, pp. 101- 104.

[8]   Alfred Fischer, John Neilson Ramsay, 1974, “Formation of Adducts in the Nitration of p- Xylene. Exchange and Rearomatization of p-Xylene Adducts.” Can. J. Chem. Vol. 52, pp. 3960-3970.

[9]   A. S. Haja Hameed, G. Ravi, A. Nixon Azariah, T. Mahalingam, P. Ramasamy, 2003, “Growth and optical characterization of organic nonlinear optical crystal: indole-3- Aldehyde.” Phys. Chem. Sol. Vol. 64, pp. 147-153.