Since the accidental discovery of carbon nanotubes (CNTs) and their fabrication by Iijima in the early 1990s , there has been a lot of research interest in this novel material. Several research works have reported practical usefulness of CNTs as composites, catalysts and molecular wires. Essentially, CNTs are tiny and single sheets of carbon atom rolled into seamlessly meshed tubes at the nanoscale level . The unique material properties of CNTs are their characteristic electrical and thermal conductivities. A CNT is either single-walled or multi-walled. Single-walled carbon nanotubes (SWCNTs) consist of a roll of one graphene sheet. The electrical behaviour of SWCNTs is determined by their chirality . Researchers in  studied the electrical behaviour of multi-walled carbon nanotubes (MWCNTs) network embedded in amorphous silicon nitride. As part of their findings, they reported that the resistance-temperature characteristic is practically linear except at very low temperatures. This suggests a metallic behaviour of the MWCNT networks. Experimental investigations have also been carried out on the scaling of resistance and electron mean-free-path of SWCNTs . Furthermore, the authors in  determined the length-dependent resistance of SWCNTs and also considered the variation of resistivity with temperature. The temperature dependent resistivity of armchair CNTs has also been studied experimentally  and the results clearly indicated metallic behavior of the SWCNT at high temperatures with resistivity increasing approximately linearly with temperature.
In this paper, we studied the temperature dependent resistivity of SWCNTs along their tubular axes in the presence of a combined direct current and laser radiation. Our results are compared with similar findings reported in reference  which reported on resistivity of these novel materials along the base helix.
Using semi-classical Boltzmann transport equation (BTE) with constant electron relaxation time, the carrier current density and axial resistivity in the SWCNT is evaluated as functions of the geometric chiral angle θh, temperature T, the real overlapping integrals for jumps along the nanotube axis Δz and the base helix Δs. This is done by following the approach of   together with the phenomenological model of a SWCNT developed in references  . Employing BTE, a chiral SWCNT placed in an electric field applied along the nanotube axisis studied under a temperature gradient ÑT such that
where f(r,p,t) is the distribution function, f0(p) is the equilibrium distribution function, v(p) is the electron velocity, r is the electron position, p is the electron dynamical momentum, t is time elapsed, τ is the electron relaxation time which is assumed to be constant and e is the electron charge. The applied dc-ac field, , whereE0 is the constant electric field, E1 and w are the amplitude and frequency of the ac field, respectively.
We employ the perturbation approach to solve Equation (1) by treating the second term on the left-hand side as a weak perturbation. In the linear approximation of ÑT and Ñμ, the solution to Equation (1) is
where ε(p) is the tight-binding energy of the electron and μ is the chemical potential.
The current density is expressed as
Substituting Equation (2) into Equation (3) gives
Employing the transformation
Equation (4) becomes
We employ the phenomenological approach of references   by considering a SWCNT as an infinitely long periodic chain of carbon atoms wrapped along a base helix. The axial current density is decomposed into the form
where Z and Y are components of the current density along the nanotube axis and the base helix, respectively.
Furthermore, we neglect the interference between the axial and helical paths connecting a pair of atoms, quantization of transverse motion can be ignored  ; an approximation that best describes doped chiral carbon nanotubes .
Resolving the current density along the tubular axis (z-axis) and base helix, we obtain
Equations (7) and (8) are transformed using
where dz and dy are the inter-atomic distance along the nanotube axis and the base helix respectively. Therefore, Z’ and Y’ become,
The integrals in Equations (9) and (10) were evaluated over the first Brillouin zone. The parameters v,p,E, ÑT and Ñμ with subscripts z and y represent the respective components along the nanotube axis and along the base helix.
The energy dispersion relation for a chiral nanotube obtained in the tight-binding approximation is expressed as:
where ε0 is the energy of an outer-shell electron in an isolated carbon atom, Δz and Δy are the real overlapping integrals for jumps along the respective coordinates, py and pz are the components of momentum tangential to the base helix and along the nanotube axis, respectively. The components vy and vz of the electron velocity v are respectively.
The carrier density of the non-degenerate electron gas can be determined by expressing the Boltzmann equilibrium distribution function f0(p) as
The normalization constant C is expressed as
where n0 is the surface charge density, In(x) is the modified Bessel function of nth order,
and k is Boltzmann’s constant.
We substitute Equations (11)-(16) into Equations (9) and (10) and simplify the integrals to obtain
where we have defined as
Also, the electrical conductivity σi(E) is expressed as
Substituting Equations (17) and (18) into Equation (6), we obtain the following expression for axial the current density as
Employing the following definitions
Equation (20) becomes
Equation (21) defines the current density and the axial component of the electrical conductivity is the coefficient of the electric field given as
The resistivity of the chiral SWCNT along its axial direction is defined as
3. Results and Discussion
In this work, we employed BTE to analytically study the axial electrical resistivity of a chiral SWCNT and obtained an expression for the axial component of the electrical resistivity, ρz in the presence of applied field E as shown in Equation (23). The ρz expression was analyzed numerically by considering a chiral SWCNT having the following parameters: dy = 1 Å, dz = 2 Å, τ = 0.3 × 10−12 s and θh = 4˚, and E0 = 6.9063 × 107 V/m, w = 1012 s−1 and E1 = 5 × 107 V/m.
Figure 1(a) shows the dependence of the axial electrical resistivity, ρz on temperature T, for various fixed values of the d.c. field, E0. It is observed that at low temperatures up to about 100 K, ρz changes slowly with temperature and the temperature dependence of ρz becomes generally linear with increasing temperature. This observation is attributed to electron-phonon interactions which cause scattering of the charge carriers along the tubular axis of the chiral SWCNT as temperature increases. The relatively low values of resistivity of SWCNT observed in Figure 1 clearly suggest that chiral SWCNTs do exhibit metallic properties. As observed in the case of circumferential resistivity , our results similarly reveal that as the electric field strength, E0 increases the axial resistivity increases significantly. This temperature dependence resistivity response of SWCNTs has been observed experimentally   . This behaviour can be explained based on the fact that as E0 is increased, the carbon atoms forming the walls of the SWCNT become more energized and tend to vibrate faster at larger amplitudes resulting in enhanced scattering of the electrons. Our study has also revealed that the resistivity of the SWCNTs decreases markedly with increasing Δy as shown in Figure 1(b).
Figure 2 shows the variation of the axial current density with temperature for selected values of the chiral angle, θh and dimensionless parameter Δz. Increasing θh results in a decrease of the resistivity of the chiral SWCNT as seen in Figure 2(a), a behaviour similar to that observed for Figure 2(a) reveals that increasing the chiral angle, θh results in a decrease of the resistivity of the chiral SWCNT. On the other hand, Figure 2(b) shows that keeping Δy constant and varying Δz decreases ρz by an order of magnitude. Also observed in Figure 2(b) is that ρz remains unchanged for all values of Δz at temperatures below 100 K but decreases steadily by small margins with increasing temperature.
Figure 1. Dependence of axial current density (ρz) on temperature (T) for: (a) fixed values of the d.c. field E0, 2E0, 3E0 and 4E0, where E0 = 6.9063 × 107 V/m. E1 = 5.0 × 107 V/m, Δy = 0.018 eV and Δz = 0.024 eV. (b) Fixed values of Δy. Δz = 0.024 eV, E1 = 5.0 × 107 V/m, E = 2E0, where E0 = 6.9063 × 107 V/m.
Figure 2. Variation of ρz with temperature for (a) fixed values of chiral angle, θh. Δz = 0.024 eV, Δy = 0.018 eV, E1 = 5.0 × 107 V/m, E = 2E0, where E0 = 6.9063 × 107 V/m. (b) The dependence of ρz on temperature for various fixed values of Δz. Δy = 0.018 eV, E1 = 5.0 × 107 V/m and E = 2E0, where E0 = 6.9063 × 107 V/m.
Figure 3. The dependence of ρz on temperature T for Δy = 0.018 eV, Δz = 0.024 eV, E1 = 5.0 × 107 V/m, E = 2E0, where E0 = 6.9063 × 107 V/m, and chiral angle, θh = 4.0˚ for the case in which (a) laser is turned and (b) laser is turned off.
On the other hand, when the a.c. source is switched off, E1 = 0, a = 0, w = 0 and becomes unity and equation (19) reduces to
Figure 3 shows the dependence of axial resistivity of the chiral SWCNTs on temperature in the presence and absence of a laser. Clearly, when the laser source is switched off, ρz decreases by three orders of magnitude. This indicates that within the temperature range under consideration, the laser field modulates the d. c. field and enhances the momentum and kinetic energy of those electrons which are deficient in energy.
Using the semi-classical approach, the axial resistivity of a chiral SWCNT induced by a laser field has been investigated and compared with an earlier work that examined the circumferential resistivity of these unique materials. Our results indicate that the conductivity of SWCNTs is similar for both directions and is significantly influenced by material parameters (Δy, Δz, θh), the strengths of the constant field E0 and laser source strength E1. The axial resistivity can be increased by increasing the d.c. field strength and decreasing the chiral angle. As observed for the circumferential case, the axial resistivity also steadily and linearly increases with the chiral angle θh and real overlapping integral along the axial direction Δy at room temperatures. Therefore, SWCNTs can be used in the design of efficient optoelectronic devices.
 Zhou, W.Y., Bai, X.D., Wang, E.E. and Xie, S.S. (2009) Synthesis, Structure, and Properties of Single-Walled Carbon Nanotubes. Advanced Materials, 21, 4565-4583.
 Ionel, S., Lepadatu, A.-M., Teodorescu, V.S., Ciurea, M.L., Iancu, V., Dragoman, M., Konstantinidis, G. and Buiculescu, R. (2011) Electrical Behavior of Multi-Walled Carbon Nanotube Network Embedded in Amorphous Silicon Nitride. Nanoscale Research Letters, 6, Article Number: 88.
 Purewal, M.S., Hong, B.H., Ravi, A., Chandra, B., Hone, J. and Kim, P. (2007) Scaling of Resistance and Electron Mean Free Path of Single-Walled Carbon Nanotubes. Physical Review Letters, 98, 186808.
 Kane, C.L., Mele, E.J., Lee, R.S., Fischer, J.E., Petit, P., Dai, H., Thess, A., et al. (1998) Temperature-Dependent Resistivity of Single-Wall Carbon Nanotubes. EPL (Europhysics Letters), 41, 683.
 Twum, A., Mensah, S.Y., Edziah, R. and Arthur, A. (2020) Laser Induced Resistivity of Chiral Single Wall Carbon Nanotubes. Journal of Physics Communications, 4, 075011.
 Mensah, S.Y. and Kangah, G.K. (1992) The Thermoelectric Effect in a Semicon Ductor Superlattice in a Non-Quantized Electric Field. Journal of Physics: Condensed Matter, 4, 919.
 Slepyan, G.Y., Maksimenko, S.A., Lakhtakia, A., Shenko, O.M.Y. and Gusakov, A.V. (1998) Electronic and Electromagnetic Properties of Nanotubes. Physical Review B, 57, 9485.
 Yevtushenko, O.M., Slepyan, G.Y., Maksimenko, S.A., Lakhtakia, A. and Romanov, D.A. (1997) Nonlinear Electron Transport Effects in a Chiral Carbon Nanotube. Physical Review Letters, 79, 1102.
 Mensah, S.Y., Allotey, F.K.A., Mensah, N.G. and Nkrumah, G. (2001) Differential Thermopower of a CNT Chiral Carbon Nanotube. Journal of Physics: Condensed Matter, 13, 5653.
 Yanagi, K., Udoguchi, H., Sagitani, S., Oshima, Y., Takenobu, T., Kataura, H., Ishida, T., Matsuda, K. and Maniwa, Y. (2010) Transport Mechanisms in Metallic and Semiconducting Single-Wall Carbon Nanotube Networks. Acs Nano, 4, 4027-4032.